Potassium Vs. Rubidium, Cesium and Francium

In some ways, potassium is a strange substance, ascausing a state of permanent relaxation known as
evidenced by its behavior in response to water. Aspotassium inhibition. Since plants depend on potassium
everyone knows, water tends to put out a fire, andfor growth, it was only logical that potassium, in the
most explosives, when exposed to sufficientform of potassium chloride, was eventually applied as
quantities of water, become ineffective. Potassium,a fertilizer. This, at least, distinguishes it from its sister
on the other hand, explodes in contact with waterelement: sodium, or sodium chloride, which can kill
and reacts violently with ice at temperatures as lowplants if administered to the soil in large enough
as ?148°F (?100°C). In a complete reversal of thequantities. Another application of potassium is in the
procedures normally followed for most substances,area pioneered by the Chinese about 800 years ago:
potassium is stored in kerosene, because it mightthe manufacture of fireworks and gunpowder from
burst into flames if exposed to moist air. Manypotassium nitrate. Like ammonium nitrate, made
aspects of potassium mirror those with regard toinfamous by its use in the 1993 World Trade Center
sodium. The two have a number of the samebombing and the Oklahoma City bombing in 1995,
applications, and in certain situations, potassium ispotassium nitrate doubles as a fertilizer.
used as a sodium substitute. Like sodium, potassiumThe three heaviest alkali metals are hardly household
is never found alone in nature; instead, it comesnames, though one of them, cesium, does have
primarily from sylvinite and carnalite, two oresseveral applications in industry. Rubidium and cesium,
containing potassium chloride. Also, like sodium,discovered in 1860 by German chemist R. W. Bunsen
potassium was first isolated in 1807 by Davy, using(1811-1899) and German physicist Gustav Robert
the process of electrolysis. A few years later, aKirchhoff (1824-1887), were the first elements ever
German chemist dubbed the newly isolated elementfound using a spectroscope. Matter emits
"kalium," apparently a derivation of the Arabic qali, forelectromagnetic radiation along various spectral lines,
"alkali"; hence the use of K as the chemical symbolwhich can be recorded using a spectroscope and
for potassium.then analyzed to discern the particular "fingerprint" of
Potassium has another similarity with sodium; althoughthe substance in question. When Bunsen and
it was not isolated until the early nineteenth century,Kirchhoff saw the bluish spectral lines emitted by one
its compounds have been in use for many centuries.of the two elements, they named it cesium, after a
The Romans, for instance, used potassiumLatin word meaning "sky blue." Cesium, which is very
carbonate, or potash, obtained from the ashes ofrare, appears primarily in compounds such as pollucite.
burned wood, to make soap. During the Middle Ages,It is used today in photoelectric cells, military infrared
the Chinese applied a form of saltpeter, potassiumlamps, radio tubes, and video equipment. During the
nitrate, in making gunpowder. And in colonial America,1940s, American physicist Norman F. Ramsey, Jr. built
potash went into the production of soap, glass, anda highly accurate atomic clock based on the natural
other products. The production of just one ton offrequencies of cesium atoms. Rubidium, by contrast,
potash required the burning of several acres' worthhas far fewer applications, and those are primarily in
of trees, a wasteful practice in more ways than one.areas of scientific research. On Earth it is found in
Though there was no environmentalist movement inpollucite, lepidolite, and carnallite. It is considerably
those days, financial concerns never go out of style.more abundant than cesium, and vastly more so than
In order to save the money lost by using up vastfrancium. Indeed, it is estimated that if all the
acres of timber, American industry in the nineteenthfrancium in Earth's crust were combined, it would
century sought another means of making potash.have a mass of about 25 grams. Francium was
The many similarities between sodium and potassiumdiscovered in 1939 by French physicist Marguerite
provided a key, and the substitution of sodiumPerey (1909-1975), student of the famous
carbonate for potassium carbonate saved millions ofFrench-Polish physicist and chemist Marie Curie
trees.(1867-1934). For about four decades, scientists had
In 1847, German chemist Justus von Lie bigbeen searching for the mysterious Element 87, and
(1803-1873) discovered potassium in living tissues. Aswhile studying the decay products of an actinium
a result, scientists became aware of the role thisisotope, actinium-227, Perey discovered that one out
alkali metal plays in sustaining life: indeed, potassium isof 100 such atoms decayed to form the
present in virtually all living cells. In the human body,undiscovered element. She named it francium, after
potassium which accounts for only 0.4% of theher home-land, France. Though the discovery of
body's mass is essential to the functioning of muscles.francium solved a mystery, the element has no
In larger quantities, however, it can be dangerous,known uses outside of its applications in research.